ࡱ> ! !bjbjT~T~ 4&66( $+++++???8w$? H: < < < < < < $?#%P` Q+` ++ ++: : V@0zHa?t|Z &  0 fx1&1&1&+H` ` ~p 1& :  Suppose you have discovered two new elements -- Quackine (Q) and Tweetine (T). You find they undergo a reaction with methane identical to free radical chain monohalogenation. Assuming the mechanisms are also identical, write the elementary steps for the reaction of Q2 or T2 with CH4. (Let X = Q or T). Use proper curved arrow formalism to represent the bonding changes taking place. Include the termination steps X = Q T 1) H1 = 2a) H2a = 2b) H2b = 3a) 3b) 3c) a) Given the following homolytic bond dissociation energies (in Kcal/mol), calculate the enthalpy of reaction (H) for the first three steps in the mechanism. Place the values of H in the spaces provided on the problem above. Show all work. Q Q 79 CH3 Q 82 H Q 119 CH3 H 104 T T 56 CH3 T 80 H T 100 b) Which of the two "halogens" would exhibit a more exothermic overall reaction with methane? Give the value of H for that "halogen". c) What is the rate-determining step (RDS) in the reaction of Q2 with CH4? Explain. d) What is the rate-determining step (RDS) in the reaction of T2 with CH4? Explain. e) Which propagation step with which element would be expected to have the highest energy of activation? Explain f) Which of the two "halogens" exhibits a greater reactivity (i.e. undergoes a faster reaction) towards methane? Explain. h) Draw a reaction-energy profile for the rate-determining step (RDS) in the reaction of T2 with CH4. Label the reactants, products, enthalpy (     " $ & * , . 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You have discovered yet another new element, Kitcarsine, Kc. It also undergoes normal monohalogenation reactions as shown below.  EMBED ChemDraw.Document.6.0  From the yields shown on the previous page, calculate the relative reactivities of primary, secondary and tertiary hydrogens (1o: 2o: 3o H) towards Kc2. Show all work.     Problem Set Chapter 4 r !! !!&!*!,!N!P!R!V!X!\!^!b!d!h!!!!!ȷȷȷȪȌ|xhvh%hf/jhf/Uho,nh4*yOJQJ^J h4*yh4*yCJOJQJ^JaJh4*yh4*yOJQJ^J h4*yh4*yCJOJQJ^JaJh4*yh4*yOJQJ^Jh4*yOJQJ^Jh4*yOJQJ^Jjh4*yUj~OP h4*yUVh4*yT!V!Z!\!`!b!f!h!!!!! 7$8$H$gd4*y$a$gd% 21h:p1Z/ =!"#$% ^5Dd $LM0  # A"4|%h_4D @=4|%h_ *87h[$|4x] |SEiJIyjAB+VD|Â* DZ-^<ʺ. 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