ࡱ> $&#p  )bjbj .4 NN84,*:=p('*)*)*)*)*)*)*$*,.RM*]M**'*'*(|)H\F/)**0*A)/^/$)/)0M*M*:*/N W:  1. Assume 25(C and plane-polarized light from the D line of a Na vapor lamp (590 nm). a. Calculate the specific rotation of pure enentiomer X if the observed rotation (a obs) is -8.4( using a 1 dm sample tube and a concentration of 0.25 g/ mL. Show an explicit calculation using the formula from your lecture notes and textbook. b. What would be the expected a obs if the concentration was 0.125 g/mL under the same conditions? 2. The specific rotation, []D, is known to be 13.52 ml/g dm for (+)-2-butanol. The optical rotation of a sample of (+/-) 2-butanol was measured to be a obs = -0.45 using a cell with a pathlength of 0.6 dm and a concentration of 0.15 g/mL. Calculate the % ee and the percentage of the (+) and (-) isomers. 3. Two students analyzed a sample of pure enantiomer Y. The first student measures a obs = +120 using a concentration of 1.0 g/mL in a 1.0 dm tube. The second student measures a obs = -120 using a concentration of 2.0 g/mL in a 1.0 dm tube. A procedure check verifies that both students did analyze the same sample and were not measuring different enantiomers. Next, a third rotation was obtained on the same sample; a obs = +60 using a concentration of 0.5 g/mL in a 1.0 dm tube. Reconcile the results; i.e., what is the actual value for specific rotation? 4. Draw Fischer projections for both enantiomers for each of the following; assign R or S to each asymmetric center. Use the mirror planes provided to help reflect the enantiomers. Remember, C-1 is at the top of a Fischer structure!  EMBED ChemDraw.Document.6.0   EMBED ChemDraw.Document.6.0   EMBED ChemDraw.Document.6.0   EMBED ChemDraw.Document.6.0  5. *DF~    ,0꼬}ie]}}hJCJaJhJ&hJB*EHH*OJQJ^JaJph hJaJ hJH*aJhJOJQJaJhJB*EHH*aJphhJB*aJphhJB*OJQJ^JaJph hJCJhJCJH*aJhJCJOJQJaJh8ECJaJ jhJCJaJhJCJaJhJCJOJQJ^JaJ$* H  "$&dh&(*,.NOPQRSTUVWXYZ[\]^_`abcdeL]L~MNfPQRSqrtvw}uc#hJB*CJOJQJ^JaJphjhJUjE hJUVj hJUjxE hJUVjgE hJUVjhJUhJCJaJhhJ5aJhJhJ5B*aJphhJOJQJaJhJB*aJphhJB*EHH*aJph hJaJ hJH*aJ$efPQ !!p#r#$0]0a$0]0gd8E0]0 $0]0a$gd8E 07$8$H$]0gd8E0dh]0^gd8E0dh]0^ f!!!!ϽmXG5-jh8EU#hJB*CJOJQJ^JaJph h8Eh8ECJOJQJ^JaJ)h8EhJB*CJOJQJ^JaJph#hJB*CJOJQJ^JaJph#h8EB*CJOJQJ^JaJph)h8Eh8EB*CJOJQJ^JaJph)h8Eh8EB*CJOJQJ^JaJphU#h8EB*CJOJQJ^JaJph)h8Eh8EB*CJOJQJ^JaJphjhJUj"hJUj E hJUVDraw Fischer projection for all stereoisomers and identify the meso structure. CH2Cl-CHF-CHF-CH2Cl 6. Complete the Fischer projections for all possible stereoisomers of 3-bromo-4-chlorolpentane-1,2-diol.  EMBED ChemDraw.Document.6.0  Identify all asymmetric centers then use the formula to determine the number of stereoisomers. Be sure to place C(1) atthe top of each Fischer projection! Then answer questions a,b,c below. a. For each isomer, assign R or S configuration to each asymmetric center . b. For each isomer, indicate whether it is optically active or inactive. c. Indicate which isomers are meso compounds, if any. 7. Consider 1-chloro-2,2,3-trimethylbutane.  EMBED ChemDraw.Document.6.0  a. Draw a Newman projection (C-1 - C-2 bond) for the most stable conformation. b. Convert your Newman projection into a Fischer projection. c. Convert your Fischer projection into a sawhorse projection.     Chem 231 PS 5.2  DATE \@ "M/d/yyyy" 8/17/2009 Optical Rotations, Fischer Projections, Organic Analysis page  PAGE 1 NAME _________________________________ due date _______________ !!!!!!n#p#r#|##########"$*%.%0%%%pp^RF>jhJUhJCJOJQJ^Jh8ECJOJQJ^J#hJB*CJOJQJ^JaJph&hJ6B*CJOJQJ^JaJph&hJ>*B*CJOJQJ^JaJph#hJB*CJOJQJ^JaJph#h8EB*CJOJQJ^JaJphhJ#hJB*CJOJQJ^JaJphh8ECJaJ h8Eh8Ejh8EUjX)h8EUj=4N h8EUVh8Er#t#v#x#z#|#~#########($$*%,%.%%%%p& 0]0^0dh]0 0]0^ 0]0`0]0$0]0a$%%%%%%%&&'l'n'p'r'v'x'|'~'''''''''''''ϽϫϽvfZfIf!h8ECJOJQJ^JmHnHuhCJOJQJ^JjhCJOJQJU^J h8Eh8ECJOJQJ^JaJhJCJOJQJ^JhJCJOJQJ^Jh~&jh~&U#hB*CJOJQJ^JaJph#hJB*CJOJQJ^JaJph#hJB*CJOJQJ^JaJphjhJUj!4hJUjnG hJUVhJp&&l'n'p't'v'z'|''''''()))) )  !`' 0]0^'j(l(x(z(|(~((()))) )h~&hJ hJCJhJCJOJQJ^J%h8E0JCJOJQJ^JmHnHuhJ0JCJOJQJ^J#jhJ0JCJOJQJU^JhJCJOJQJ^J ,1h/ =!8"8#T$%  Dd -0  # A"d lRe3YwV@ Di@=8 lRe3YwVPlʩBJ5H(RPRE"-UK+JQդ(MS0.%!YܱP#Λ{ޛ73{Vچaw3^S[3yHJbHzbf`=9s>8&K{0aΔUطW6%:;IT}zc9D!1[KMxQX?qI|pe alxKs^T-}W%dž5-~Dw)hh_k`_37%["7('n|j`&pgRРgt5v$ًm?ŝٱm!}.NBU>.쾡ȵ:eە^==.*3#䞅6:1`,嫄㬰촥륰ڳ`Ÿu\)&<ҽg8qHgL5qOv;`N; ?tOv.4%J<)=⩡S#E<5R?2O_n})w2/4?\Kln7SK]&;`n4p7C>4oǰ7#߸ť<񤳲 ľ7on9ڊߝC +H'i|6G7}0 (#ˀhq#^J}׼DcIB'Aea?沟Bm}H'pq w8('1{tkNS;Cbg;`MF'C.9{4=Y{{ib]tRcIl=n:!)K]I*4]]-qnNI)p^ kHE. %vh[\t~^b}$M].o`? o~ ~~{^}.M˼s-{=n:~{vZu{4)G$cO} ~{|.>%9`o=f;.xjTo Xw jgwMoe٦ep18iX4Ti9&fzX±X4Rf9X@i"R' ,Q 3L4W<xē!e,?h6SI Hz,uʳUԢ'fV!$7`ΞP/jtu}~0G PۨѺA,{`LnT_=^a.1-ƨΪ`_ J>Q|XgZ'1ShM:c'J=!X#ɲg/W尞w|$M(~6` d0EPυ<2.Oꁕ~)EOq|e`o;ExE}y8|ŷd bT葻/ߛNַ" v3lT=/F%]!p6Y!m>i^18_6j '+zslo _"+1ylh( dDyf3>Xb0Zg7",17͍7"%I 9/IU%ArAWIH @U\|$I&$ri3lSGwl bzAohKo۳u`Whpg{hKoؿ;s{xp (L[&uk,jCOn5YX30uXI0ZV e]zX(qtոנKp g'ȢԠ=􉠠#|U PxLЕa )bghBM9s|%gE%jtWko FLVm,WȌwb'1Ti Gbt5DdVj"\ۂW!nx(^S,0 d‹}ܓe ( c<{.Q6n`Cx0CR zIl)Dq_ͫC33&_{sEjҺ>(㥫kG}#ڱg%<A;G@kp8 =UTIJE- hvE|Pe*,jҺU6M(HMPKn_!+ׂ´ M@ଭ[A|eQĎuDU-,R1 8L)c;H`!L1ų%`=+Cb2]P(sys|V"`k>p2؋qTo{_%dԺ]WYo|m .Ga;GUzD[1M8LP/'-kȘ>*ϣ/Ҟ?ȐۡgEf|.I]-P꫈Q 5Ox7W$(S,;uī7'^GOO6«|- ߏP'LZ~^e>n6#ci&I DR5'yەL[['erOSbہFlW3XGB֡GԾF߹l?~ΣRJPZYߑlm;nkJ\3ؚ6R:>aW\d_+!kfWAîz*V^dI~?VlҎ7bG=#j!ܿڧױF 1lQl*N4|wdO%U<u2XTRSI'J:XwϷ|G%hpl[i(Ǵ(+bټuĢϮ`el],/I&k&oDI:7*uMǰK:ݗѲy3LQ6WŲy Ev˧~$i`|/<-7et| {_ܩ/- =bu,^Wn wAϟ{J?@ABCDEFGHIJKLMNOPQWTUVikYZ[\]^_`abcdefghjlomnrstuvwxyz{|}~Root Entry" F '*Data d<WordDocument!.4ObjectPool$ Y _1158646119!mA. Y YOle EPRINT(?@ABCDEFJKLMNOPQRSTUVWXYZ[\_bcdefghijklmnopqrstuvwxyz{ VjCD0100ChemDraw 8.0u])?]t  @@' :;<   `  3xx# $$$$2$ArialTimes New RomanxXX$dg(XX$lfJ  EMF@..<@J;@m@ LPt   TTA<GJ;@m@ LPa,   TTH<NJ;@m@ LPn, 8  TTN<QJ;@m@8 LP- Q  TTR<XJ;@m@Q LP1, z  TTY<\J;@m@z LP-   TT]<cJ;@m@ LPo,   TTd<fJ;@m@ LPl % FL@CDIFVjCD0100ChemDraw 8.0u])?]t  @@' :;<   `  3xx# $$$$2$ArialTimes New RomanxXX$dg(XX$d'`)$$ṳ6? i`W: 7>G S 7i` 7fjG 7*fB3 7L$fjG &fjG  ' &$TMFCuFCfW-Q#`Mě: +7 ̤6B̤6? ̤E#`OH          L]TO?])?]t  5This label has conflicting or unassignable charges. 2-methylbutan-1-olFDMHCGRTS? N   x (XP`5(MeOH `` vAAxW `` DeDp  2 XD 2-methylbutan-1-olArialTimes New RomanF4%MDLSKXY Ariald 0   XeaArialZ2-methylbutan-1-ol 0 !% ED{E!% 2DE!% QD{E!% qDE!Me!% Z2DU@E! Z2DU$E ' "4Me6=  Z2DU@E< !O%b _Dʟ%E '  '  '  '  ' % % CONTENTS;_1158646136 !mA. Y YOle EPRINT <8+dd'`)$$ṳ6? i`W: 7>G S 7i` 7fjG 7*fB3 7L$fjG &fjG   '  &$TMFCuFCfW-Q#`Mě: +7 ̤6B̤6? ̤E#`OH          L]TO?])?]t 5This label has conflicting or unassignable charges. 2-methylbutan-1-ollO EMF8+7   R KRpL"ArialEewp8wDwp}w:w#gHDwp}w:w((8KPDw\dDw h2EP4P| Xodp}wwxw:w||dv%   &% 86{ % &% (  ) t  % ( '%  % ( % &% {68 % &% (  ) t  % ( '%  % ( % &% j86{ % &% (  ) t  % ( '% Rp8"Arial xx@@Lwxwh|84@ @0n|@xf4P XoO@|wxw:w||dv% a%  % ( % aRp"Arial%ww:wP<4P XoDwx%TLwxw:w||dv% a TT=G@'@aLPME  TTHN@'@LPe, % &% 86 % &% (   % ( '% %  %  % ( %  %   TT+23A@'@ LPB8 )  TT427A@'@) LPr % &% {6 % &% (  )  % ( '% % Q%  % ( % Q% Q TTck@'@QLPC8  TTmo@'@LPl % &% j86o % &% (   % ( '% % t %  % ( % t Rp"Arial(`t>@..ACO@'@it LPcp& t  TTDAJO@'@t LPhl, t  TTKAMO@'@t LPlK t  TTMASO@'@t LPoe, t  TTTAWO@'@t LPro  t  TTXA^O@'@ t LPok, 5t  TT_AbO@'@5t LP-  Nt  TTcAiO@'@Nt LP2a, xt  TTiAlO@'@xt LP-R t  TTmAwO@'@t LPmpE t  TTwA}O@'@t LPeD, t  TT~AO@'@t LPtE t  TTAO@'@t LPhl, 8t  TTAO@'@8t LPyn ]t  TTAO@'@]t LPle nt  TTAO@'@nt LPb9, t  TTAO@'@t LPud, t  TTAO@'@t LPto t  TTAO@'@t LPaC,  t  TTAO@'@ t LPnt, ) t  TTAO@'@) t LPe , % FCDIFVjCD0100ChemDraw 8.02rff$r  @@' :;<   `  3xx# $$$$2$ArialTimes New RomanxXX$dg(XX$d'`)$$2̈E.y^ 7!p y 7!pN 7p` 7*p`]<,$p` &p `  ' &$`^%`p#`MeV  #+7̈D̈̈#`Br_ "+72E.#`Cl         !  # 3s"rffrff$r $5This label has conflicting or unassignable charges. +1-bromo-4-chloro-2-methylbutaneFDMHCGRTSA*QO  x (XP`5YY "!#MeBrCl `` O^Oe `` BBB  `` UK  $$# `1-bromo-4-chloro-2-methylbutaneArialTimes New RomanF|oMDLSKXY Ariald 0  0 k X{ArialZ1-bromo-4-chloro-2-methylbutane 0 !% D"E!% DDE!% jE"E!% ZEE!Me!% $DnE! $D.(E ' "4Me6=  $DnE< !#Br% D,E!Cl% E E '  '  '  '  '  ' % % ObjInfo CONTENTS_1158646145!mA. Y YOle 1 VjCD0100ChemDraw 8.02rff$r  @@' :;<   `  3xx# $$$$2$ArialTimes New RomanxXX$dg(XX$dd'`)$$2̈E.y^ 7!p y 7!pN 7p` 7*p`]<,$p` &p `   '  &$`^%`p#`MeV #+7̈D̈̈#`Br_ +72E.#`Cl             3s"rffrff$r !5This label has conflicting or unassignable charges. +1-bromo-4-chloro-2-methylbutane VjCD0100ChemDraw 8.0EXY2X  @@' :;<   `  3xx# $$$$2$ArialTimEPRINTX!ObjInfo2CONTENTS3_1158672397!mA. Y YlY8{ ( EMF!  @u \; / KRpL"ArialEewp8wDwp}w:w#gHDwp}w:w((8KPDw\dDw h2EP4P| Xodp}wwxw:w||dv%   &%  6 $ % &% (  M &  % ( '%  % ( % &% d $6  % &% (  M &  % ( '%  % ( % &%  6d $ % &% (  M &  % ( '% Rp8"Arial xx@@Lwxwh|84@ @0n|@xf4P XoO@|wxw:w||dv% r %  % ( % r Rp"Arial%ww:wP<4P XoDwx%TLwxw:w||dv% r  TT 'Ć@ʅ@r LPO?   TT'Ć@ʅ@ LPH8 % &%  $6 l % &% (    % ( '% % @ %  % ( % @ % @  TT,5&Ć@ʅ@@ LPO?   TT6>&Ć@ʅ@ LPH8 % &% d $6` g % &% (    % ( '%  % ( % &%  6+ ! % &% (    % ( '% % @ & %  % ( % @ & Rp"Arial(`t>@..̤_d ̤n#`OH–5| +7(} Mx[Mx M#`OHƜi 7                    XzXY2X &ChemDraw can't interpret this label. pentane-1,3-diolFDMHCGRTSC_Nr  x (XP`5OHOH `` xTx `` fIf  g pentane-1,3-diolArialTimes New RomanFMDLSKXY Ariald 0   Xa]ArialZpentane-1,3-diol 0 !% 1^EOE!% Z fEUE!% %mEOE!% uEUE!O%b 8^E%E!O%b 3mE9$E!% (|EE '  '  '  '  '  ' % % es New RomanxXX$dg(XX$dd'`$$$E̤_d ~c 7 !p 7 n|  !' 7$̌c +7 ̤_>̤_d ̤n#`OH–5| +7(} Mx[Mx M#`OHƜi 7                    XzXY2X &ChemDraw can't interpret this label. pentane-1,3-diolOle GObjInfoHCONTENTSI_1312036669!mA. Y YVjCD0100ChemDraw 8.03)X5u۴ g @@' :;<   `  1A @cxx# $$$$2$ArialTimes New Romanx,, 8 ` g(,, 8 `dd'`2$$;:X5u۴YR:@Y 7uLY 7 LThis isolated bond is probably not intended to have chemical significance. &;:W 5u4 'R:  7(u  7) LThis isolated bond is probably not intended to have chemical significance.'( *;:״5u۴+R:@  7,uL  7-  LThis isolated bond is probably not intended to have chemical significance.+, .@13)@Dd3%  &ChemDraw can't interpret this label.mirror plane !mA. CS ChemDraw DrawingChemDraw Interchange FormatChemDraw.Document.6.09qOle ]EPRINTq#CompObj^~ObjInfo`lf] *{ EMF#@F, EMF+@``F EMF+@ "@ @ !@ 0@?0@ #>2@ZD DD4D@0$BARIAL@H<h?@, N^D_DH!b    RpArialMonotype:Arial Regular:VePS"| 8SSx/N}DN@N߸D 0S"|xSS]L |(|"|||8N8TN! ~hKS$dv% TTAALPH % F`TEMF+*@$??@, NmD_DO   % TTAALPO % FEMF+*@$??@@4VA? @ DUpD4DЄD: $$==_888 % % W$6 % % $$AA( : FpdEMF+@@4VA? @ 4DЄDhȰD`jD: $$==_888 % % W$ X % % $$AA( : FpdEMF+@@4VA? @ hȰD`jDDЄD: $$==_888 % % W$X G % % $$AA( : FpdEMF+@@4VA? @ DЄDD`jD: $$==_888 % % W$)G qX % % $$AA( : Fl`EMF+@0$BARIAL@, :DDC   % TTEMAAELPC % F`TEMF+*@$??@, WEDH   % TTOWAAOLPH % FEMF+*@$??@0$۫zBARIAL@, WE*D3   ( RpArialMonotype:Arial Regular:VePS"| 8SS `/N},N@N_DH<|`|]|| | M" @wؚ|| |wM"!+w @w dv% TTX]AAXLP3% FEMF+*@$??@@4VA? @ D`jDCDD: $$==_888 % % W$%FqX ;a % % $$AA( : Fl`EMF+@0$BARIAL@, D@!DO   ( RpArialMonotype:Arial Regular:VePS"| 8SS x/N}DN@ND 0`T|`|]|| | M" @w0ؚ|| |wM"!+w @w dv% TTfuAAsLPO % F`TEMF+*@$??@, hɴD@!DH   % TTfuAAsLPH % FEMF+*@$??@@4VA? @ hȰD`jDhȰDP8D: $$==_888 % % W$sX X% % $$AA( : Fl`EMF+@0$BARIAL@, /DDB   % TTAALPB % F`TEMF+*@$??@, qDDr   % TT  AA LPr% FEMF+*@$??@@4VA? @ DЄDDD: $$==_888 % % W$G G % % $$AA( : Fl`EMF+@0$BARIAL@, z*D@!DC   % TT"f*uAA"sLPC % F`TEMF+*@$??@, zD@!Dl   % TT,f.uAA,sLPl% FEMF+*@$??@@4VA? @ D`jDDP8D: $$==_888 % % W$%s)qX qX% % $$AA( : FEMF+@CDIFVjCD0100ChemDraw 11.0f&O̴jff` 7@ @@' :;E<  BCD `  3xx# $$$$2$ArialTimes New RomanxXX$dg(XX$d'`$$f&O̴jff`pu +7fftyf&m̴jty#`OH 7p& 9  pL  ` +7ff`f&|`̬`#`CH3R& +7ffV&Υf&O&ΥVY#`OH9  #+7ff9-@9-ffF#`BrRL "+7ffVLf&OLVz#`Cl              !  #  Ldg]gt)??" FEMF+@  VjCD0100ChemDraw 11.0f&O̴jff` 7@ @@' :;E<  BCD `  3xx# $$$$2$ArialTimes New RomanxXX$dg(XX$dd'CONTENTSa_1198440671!mA. Y YOle |ObjInfo }`$$f&O̴jff`pu +7fftyf&m̴jty#`OH 7p& 9  pL  ` +7ff`f&|`̬`#`CH3R& +7ffV&Υf&O&ΥVY#`OH9  #+7ff9-@9-ffF#`BrRL "+7ffVLf&OLVz#`Cl              !  #  VjCD0100ChemDraw 8.0ZAK5_ L @@' :;<  CONTENTS~r1TableB/SummaryInformation(#DocumentSummaryInformation8  `  3xx# $$$$2$ArialTimes New Romanx,, 8 ` g(,, 8 `dd'`W$$ZAK5_e +V $7Tc %e o 'x_ )7Xx_5~Dn8+‡Jx_ Lx3_  M  LJ'_;_;xA_#`Me ۫1EV ++7A25E^St%.E^S5E[#`Cl 10\o -7Y10jT(tO10\o  PO0\o  Q PO~50kLq.0k50"x#`Me 'U /7Z gP,YS 'U T''U  U TSVg WZAK W#`Me 'p 17[ gk.t< 'p != *'p " > #=<Wmlmlx#`Me  &   (  *  ,   .   0  2 Oh+'0  8 D P \hpx12GCCCD񼏖Oߩɸ;{Q2~b 2iYv(etW 4 ,DZo8gLi[O);Q.Ez{;4MSwtƞn6y{$ۇo{z~̀=K4دdwjW5`0w4أYwdߡ.cl]l?REle\]d]=7``Uzλ݀(chM .Iv._z:2`g: I{Iaoc--f1o1էkV}VޡVŞy/1`d& g̩;fn`o4.=޼ `fy6`w0v:֥3`2s&Pz:2`)^l0sZkJc4އ{9:2! vxy0c`w|Ѐ}4 -_24gmfܧ_31 yl7zM^l],v^Āc.3ל߲I5_Tx|wlQY(8{ D>O^} pqq68!8 񘇪y*lp6+Vx.`%9%ZLNIxx I0O>\|M'yD:+r`W$z >I(!-Ϥ),vF8Hg!pIJ\+ 'r;@<f,$ukj7pKwEkfV5:'\=Ū2?hl2Fd!<6e*mXy1[pe{(!$Nɠ}oF"x/DDZkS%llN@۔*weހwF>NS)=52<0XX@])b3Fj _z39Jyj ퟀw?v?&~|!MJ\(xV[ ,*rLE8&KEn3[j̉ME&2WjGqL0~LU:SEI%$w;&v6:[=흻>ǧ§6< I 8>zg &6}Ҋ6+-/6qwzTaQlzn] [pB#tEt>LAXDd7#m(l ҷיiC_r'B"qa*t&#aHġyf!k.J6^} ^Vx<>,ﵳ/Hè&;79A>'6^ͨW$S٩~H=:9!@<*9g'e~و昰*]Q@L^N(b~| }\Ǒ"c+8@#[f]BԄ= rT3GYwΐsp^9U]re{ocRf?=ah1C.[t@-FqY:3ʽE, /,Uޖ|txe 0M (CW岘|ۋ\ԭ Mٱ<1#,M+jǿ|;׌|iQy{@t-ڨ|Br7a| v$Sb>7Sֱh_dP>#Ay&) M`m3uA#m9o1W6&i!༹)\5md2vOcuh^)}bY 65jh "a=jjgsBe +#oqIWweC)D9I$9I6$IhOsl{fOoxշe'z8gå6іڮ{{´F^?4辱?tY1ڦ::?ǠW}5iz~鱫6Ыg=<r=eˑ;}{o3S7">E.5س6wҶ XC6jOU*&T?o> T5~&;w/H1W`^u#\_ވdco1~&]{S-Mxa {S,MM57MM17ņ)&22\)Kr{IwUA܊%K=լŹĖiҙ5m7w-Mk]gmb'~U;l}&v?|ܷ-8vm2b7ẕ8v.bwY`m]6[0BM-rvAmmz,؛ _#̱`}&:Vm}'L}{;4b{̱;9v.vmLIzأqswZ`c1M+~<Š.c6xk[;ZZ[|=bjpVE"N!k?" )p?LùtZ6D$AI*r .'(Xl6n -˅H}.ئOlX7+˥8YMjTVׂ 2%QEސĥ OQ֘I@),p㱉p%KH /!}"}"8qd&M%_ 0kefh%p'. ZH*giJ^QE^V)'_I5;7QRT(HTy F tݥExMfNijJPXCl,OlpW5 4xHL3RB GJ =ORE!QfFH='%Yħ\T?$5nyA_,$IS2k}h5}2\aպ ԔP[Śnvp' 07')I8I9#)$nT2')I8IUPP$ qPPuGILrt)} ݤ-miJ#x,N Ɵ?ZC/?C2&ww25LlX&vn=C1?b۾3/ ?Dd Fy0  # A2 N$z]"i`! N$z! Q> hbD]xYMlE~3^_@ B[4IE-М㸩cGNHKe,KOP8Vp@j$ĭDW Zռ{'e#DkRYd0"R]ޛEm mʹ˓,n}ok)Ih\VJ;[SYħyk HպUkݕ%\.-D0kAQ"D0A< $΀8cA  E`: T@AƊ(uj0R?Km׺dЇW[*> %kVZ]Y+t@$tQ]W"{㯮A F@K%3f$f0%8HJSqpP"+׈J*> %kVZ]Y+t@$%8q&tSƀ8Jf0HW`8(JqD_5[pf[㾹bo7Lx73B4=8\"B,N.bqRZS"B,.-%i] Yܨc1B,"B,"u, @,=HձH/ecֈ/o ĺwtwT^C?ہSX>qխ&6r x+:WkeI/JtDcWf65_YӀ cl-oQ6t؁G>/chؿۇ!דPu g@ټ3,zllM(;q{7ㇰ1Ӊb# # H`=P{L mU"Q 0#62/ y. I߂) ;3?kmk93 5!gyf|o՝Ц?FqD0zTQ-l ׎ÊqTh#hyTzIO2Ԉ3ˎ7g<N g:ܤN#8:sN%RNt2q&ңITg "15::7,Cmi" V ikuHp%m^HBZ/|w2O-lݥ+Y waR*!mBXVA ݆.6 -թ׏0Ԥ30géL 3'p'"\$)=>7!/ ?~ Q8  !wv7}D.< 0{xoE.ʂj}8rAE{ӈ !k(Y<>bc㟀nFsuͭem m욨pN6֦𣧻=^ؑc'<\ VF`W18_SJ ElwB KV`O,Ȣ &XXXDZ&csLcDسpތ9;42P^&-! The絇8=T ">>->.I=׆J׿g Dd s 0  # A"E )g;^,Fi֙C,! )i@= )g;^,Fi֙C,#f`W xZ}lޏKaE ^J{ZLA6[I) Qn|"xl!QMh0bH` lةld#[̻y{Җ;Bryssy<㽭!"ǁ^CHwE>) "KD 9?E5[@((A` 8f.h׻*I$BJ3or쀟|9dZ"rSt#"_KOH׋ y#UP/}M:e:y cT.(o#1fiM4)qĝW?n^\u~g|σxg] aJ@JxB6ZiT!TMJ,HkcfY-!ۈ^ e-8YY&k}|J#E/iaFQI1 #5 ]Lv>&]I/IA;O :Uɏ ߧTXvD1 mGMqܲ첨 ]E~QKvV}jg?OMP#7AI=x{xxnX!ru52-Ge5 G#gx1uZ_ܕ sB1 #d_Zڤ} ޖʷ[0!g'Nwx"x_'eҔ (i?0 9^:}!܏F9<4}+Pc:@k[.V Z\k?k9JBF's3}N=FA&uCE=m{}%]&1o'%;,jz̑p΄83`g0m;a3`xڞnk  CzT(8ץ;U6.ueqKN/=M|Qի+I}<.Ϻr[=3ig@r3,tlhf63m =D}=4}GBV135}&QA e[&r㝨dj.cĜy zpo{k-wM̻֓Wi1Cn7?[Pƨw, 8@qD=c=8l=XVލj^eb/3#孡?=܈w| wiP]уڇþ:_ ;6?϶L?n끿Yve{ٖť}o|o|`lS|9 u2qiXW(S^n[<䒳y m9sn)ͨL]&QaF=%NO$k3 ̈1D&UWl42Y̺Jf fyOIl?>7bܟ婕!يڒ$#lKhԌDѯ, 6z׿5xTX bBsvTl\۸[ k74?mn=~lQ[\iD cRϦ4v:kuoz Yi;HL0:T)ԅ%PmsVbW)bNE3C Tnb:VfM+eh:2 !c)lCK&?Dzu;*e hRf'kIeevm6&E&jv!_(c(I#F]yVI$IODI AX;1IwHOu~U?!9 ;*rb姫ah+', 2W? V #A˵xE{D;2B%ؐ]WK)!n7WRbFn@:kp0%[_IJ^f!v2@y<(\H"e|[p !QPaJƐ(E(xDqk+щ!QPF7D@ DESBZ?*8j74|urN}Dz.ҵR4vK@K({t6FAS CDd Z0  # A2g&}3/5fe4i`!g&}3/5fLb{F axڭXklU>smm ![.J )`@Bkb"1>"@ DA4DSeBh$Eb(Y=sgwfwvs{sJfhpN||e{;&1>`?aٗ5Ɓ=DZ&oտ >3^ +v%טuوu-q9NL|$Id|*AXtXNS1+WyU}F5XFu͍FIMrMz9/= `9 8}(c&Z9Ub( XEcaB&*1M.ɉ鶅n!N8|Vq\?4 x#ڄQY(ad7&83dkB>y@hbf gjw {)(ET[yϢD=mS}h1k+x7V{`M*^=BJT޻Hr$ ]RP:pE3#^"ۻv^heåQ" ĚE N-ϊ)"["6Ɨh̋-R3C{X0TNKuQc+[ _`n.G -.$5 %896sVbKKeei(fҸq w~ [nXN%[ʕO­gWnTֹHB$8e N'Eg]YΦ.vA_#(R|BTR 5|j3RJ]@4;$K@bn xlr(!9qCd$vjR ,Tŭ-V> BE ;yli>ž8}(|[}v?~~~Z_7Wq&# PKO]&$U>dzٲ5dz܆ճنJðڝ0q÷MT{LrJWz;XOqrNu|5HdRAJ%D8b Normal.dotmmartin.larter3Microsoft Office Word@e@O@6@ 4 ՜.+,0 hp  GCCCD  12 Title^ 2 0@P`p2( 0@P`p 0@P`p 0@P`p 0@P`p 0@P`p 0@P`p8XV~_HmH nH sH tH @`@ NormalCJ_HaJmH sH tH DA`D Default Paragraph FontViV  Table Normal :V 44 la (k (No List 4@4 Header  !4 4 Footer  !>B@> Body TextCJOJQJ^JV/"V Default 7$8$H$!B*CJ_HaJmH phsH tH .)@1.  Page NumberHBH 8E Balloon TextCJOJQJ^JaJN/QN 8EBalloon Text CharCJOJQJ^JaJPK![Content_Types].xmlj0Eжr(΢Iw},-j4 wP-t#bΙ{UTU^hd}㨫)*1P' ^W0)T9<l#$yi};~@(Hu* Dנz/0ǰ $ X3aZ,D0j~3߶b~i>3\`?/[G\!-Rk.sԻ..a濭?PK!֧6 _rels/.relsj0 }Q%v/C/}(h"O = C?hv=Ʌ%[xp{۵_Pѣ<1H0ORBdJE4b$q_6LR7`0̞O,En7Lib/SeеPK!kytheme/theme/themeManager.xml M @}w7c(EbˮCAǠҟ7՛K Y, e.|,H,lxɴIsQ}#Ր ֵ+!,^$j=GW)E+& 8PK!Ptheme/theme/theme1.xmlYOo6w toc'vuر-MniP@I}úama[إ4:lЯGRX^6؊>$ !)O^rC$y@/yH*񄴽)޵߻UDb`}"qۋJחX^)I`nEp)liV[]1M<OP6r=zgbIguSebORD۫qu gZo~ٺlAplxpT0+[}`jzAV2Fi@qv֬5\|ʜ̭NleXdsjcs7f W+Ն7`g ȘJj|h(KD- dXiJ؇(x$( :;˹! I_TS 1?E??ZBΪmU/?~xY'y5g&΋/ɋ>GMGeD3Vq%'#q$8K)fw9:ĵ x}rxwr:\TZaG*y8IjbRc|XŻǿI u3KGnD1NIBs RuK>V.EL+M2#'fi ~V vl{u8zH *:(W☕ ~JTe\O*tHGHY}KNP*ݾ˦TѼ9/#A7qZ$*c?qUnwN%Oi4 =3ڗP 1Pm \\9Mؓ2aD];Yt\[x]}Wr|]g- eW )6-rCSj id DЇAΜIqbJ#x꺃 6k#ASh&ʌt(Q%p%m&]caSl=X\P1Mh9MVdDAaVB[݈fJíP|8 քAV^f Hn- "d>znNJ ة>b&2vKyϼD:,AGm\nziÙ.uχYC6OMf3or$5NHT[XF64T,ќM0E)`#5XY`פ;%1U٥m;R>QD DcpU'&LE/pm%]8firS4d 7y\`JnίI R3U~7+׸#m qBiDi*L69mY&iHE=(K&N!V.KeLDĕ{D vEꦚdeNƟe(MN9ߜR6&3(a/DUz<{ˊYȳV)9Z[4^n5!J?Q3eBoCM m<.vpIYfZY_p[=al-Y}Nc͙ŋ4vfavl'SA8|*u{-ߟ0%M07%<ҍPK! ѐ'theme/theme/_rels/themeManager.xml.relsM 0wooӺ&݈Э5 6?$Q ,.aic21h:qm@RN;d`o7gK(M&$R(.1r'JЊT8V"AȻHu}|$b{P8g/]QAsم(#L[PK-![Content_Types].xmlPK-!֧6 +_rels/.relsPK-!kytheme/theme/themeManager.xmlPK-!Ptheme/theme/theme1.xmlPK-! ѐ' theme/theme/_rels/themeManager.xml.relsPK] j 4 !%' ) &er#p& ) Rqsv j ::::::2<}!8@0(  B S  ? mpCMnqz$(/<TYb f h k msntOQ C O  ( [ f h k 3333333333333333RtR| } % f h k myipRtR| } h k D:-n^AB8\ME?:URJp@~W$=pmh ^`hH.h^`.hpLp^p`L.h@ @ ^@ `.h^`.hL^`L.h^`.h^`.hPLP^P`L.^`o(. ^`hH. pLp^p`LhH. @ @ ^@ `hH. ^`hH. L^`LhH. ^`hH. ^`hH. PLP^P`LhH.h^`.h^`.hpLp^p`L.h@ @ ^@ `.h^`.hL^`L.h^`.h^`.hPLP^P`L.h ^`hH.h ^`hH.h pLp^p`LhH.h @ @ ^@ `hH.h ^`hH.h L^`LhH.h ^`hH.h ^`hH.h PLP^P`LhH.h^`.h^`.hpLp^p`L.h@ @ ^@ `.h^`.hL^`L.h^`.h^`.hPLP^P`L.h^`.h^`.hpLp^p`L.h@ @ ^@ `.h^`.hL^`L.h^`.h^`.hPLP^P`L.ABD:-@~W\ME$=pm:UR                                    ~&E *8EYqJ @NN(VNNXj XX X XXX$@X UnknownG* Times New Roman5Symbol?. * ArialArial5. *aTahomaA BCambria Math"1hw&&   !8T4d  2QHX ?2!xx12GCCCD martin.larter$      CompObjy  F'Microsoft Office Word 97-2003 Document MSWordDocWord.Document.89q